In the presence of Yb metal, diaryl ketones react nucleophilically with octan-2-one, acetonitrile, epoxides, and CO2 to give the corresponding unsymmetrical pinacols, α-hydroxy ketones, 1,3-diols, and α-hydroxy carboxylic acids, respectively.
Z. Hou, K. Takamine, O. Aoki, H. Shiraishi, Y. Fujiwara and H. Taniguchi, J. Chem. Soc., Chem. Commun., 1988, 668 DOI: 10.1039/C39880000668
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