Diastereoisomers of three ethylenediaminetetra-3-propionatochromate(III) ions and the (S)-propane-1,2-diamine analogues, have been synthesized and characterized by 2H n.m.r. and circular dichroism (c.d.) spectroscopy; a facile C–N bond cleavage occurs during decomposition on heating at 60 °C, and this process was followed by spectroscopy.
S. Kaizaki and M. Hayashi, J. Chem. Soc., Chem. Commun., 1988, 613 DOI: 10.1039/C39880000613
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