The aminyl–borane radical MeṄH→BH3, an isoelectronic nitrogen–boron bonded counterpart of the isopropyl radical, readily transfers a β-hydrogen atom from boron to simple alkenes to form alkyl radicals.
J. N. Kirwan and B. P. Roberts, J. Chem. Soc., Chem. Commun., 1988, 480 DOI: 10.1039/C39880000480
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