The cluster-derived bimetallic catalysts prepared from SiO2-supported Rh4Fe, Rh4Fe2, Pt3Fe3, PtFe4, Pd6Fe6, and PdFe4 carbonyl clusters exhibit high catalytic activities and selectivities for formation of oxygenates, consisting mainly of methanol and ethanol, from CO + H2.
A. Fukuoka, T. Kimura and M. Ichikawa, J. Chem. Soc., Chem. Commun., 1988, 428 DOI: 10.1039/C39880000428
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