New synthetic models for the bleomycin (BLM) metal ion binding site which contain the terminal binding group of imidazole (HAPH) or S–Me, SCH2C6H4OMe, and –SH (SAPH 1–3) derivatives have been prepared; FeII(HAPH)/O2 yielded 53%, and FeII(HPAH)/H2O2 63%, of the HO· generated by FeII(BLM)/O2.
T. J. Lomis, J. F. Siuda and R. E. Shepherd, J. Chem. Soc., Chem. Commun., 1988, 290 DOI: 10.1039/C39880000290
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...