Tetrabutylammonium alkyl- and aryl-thiolates initiate the quantitative polymerization of acrylic acid esters at room temperature to form isotactic polymers having a narrow molecular weight distribution.
M. T. Reetz and R. Ostarek, J. Chem. Soc., Chem. Commun., 1988, 213 DOI: 10.1039/C39880000213
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