Reactions of stoicheiometric quantities of sulphur or selenium, bromine, and arsenic pentafluoride in liquid SO2 lead to the quantitative syntheses of crystalline Br2M+MMBr(AsF6–), (M = S, Se), the structures of which were determined by single crystal X-ray diffraction.
J. Passmore, M. Tajik and P. S. White, J. Chem. Soc., Chem. Commun., 1988, 175 DOI: 10.1039/C39880000175
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