The formation of the 2-t-butyl-4,6-dimethyl-4,5,6-trinitrocyclohex-2-enones (2) and (3) on reaction of 2-t-butyl-4,6-dimethyl-4-nitrocyclohexa-2,5-dienone (1) with nitrogen dioxide proceeds via 4,5-addition of nitrogen dioxide to the 6-nitrocyclohexa-2,4-dienone (5), the product of a 1,3-nitro migration.
J. W. Blunt, M. P. Hartshorn, R. G. Jensen, A. G. Waller and G. J. Wright, J. Chem. Soc., Chem. Commun., 1988, 62 DOI: 10.1039/C39880000062
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