Enantiospecific syntheses of (6R,8R)- and (6S,8S)-2-methyl-6,8-dihydroxynon-2E-enoic acids and their corresponding caprylcysteamine thiol esters are described; these thiol esters are incorporated efficiently and enantiospecifically into nonactin, thereby establishing the direct precursor role of these units in nonactin biosynthesis.
Z. M. Spavold and J. A. Robinson, J. Chem. Soc., Chem. Commun., 1988, 4 DOI: 10.1039/C39880000004
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