Issue 11, 1987

What makes hydrocyanic acid a normal acid?

Abstract

A classical intersecting-state model is applied to the study of proton-transfer reactions of HCN with oxygen and nitrogen bases. According to theory, what makes these proton transfer fast processes is the involvement of the CN bond together with the XH bonds in the reaction co-ordinate, which increases the average bond order of the transition state and decreases the reaction energy barrier. The slow reactions of most carbon acids and the intermediate behaviour of some other carbon acids such as the malononitriles and ethyl vinyl ether are also discussed within this theoretical formalism.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1987, 1655-1658

What makes hydrocyanic acid a normal acid?

S. J. Formosinho and V. M. S. Gil, J. Chem. Soc., Perkin Trans. 2, 1987, 1655 DOI: 10.1039/P29870001655

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements