We describe approaches to thromboxane A2 analogues (3), (4), and (32) which contain 2,6-dioxabicyclo[3.2.1]octane and 2,6-dioxatricyclo[3.3.1.03,7]nonane ring systems. Both were derived from 2-substituted 8-oxabicyclo[3.2.1]oct-6-en-3-ones, which were in turn prepared by cycloadditions of suitable oxyallyls and furans.
K. G. Bowers, J. Mann, E. B. Walsh and O. W. Howarth, J. Chem. Soc., Perkin Trans. 1, 1987, 1657 DOI: 10.1039/P19870001657
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