The reaction of aryl halides (1a–g) with octacarbonyldicobalt in the presence of methyl iodide and sodium hydroxide under phase-transfer conditions was found to give a mixture of aryl methyl ketones (2a–g) and aromatic carboxylic acids (3a–h). From vinyl halides (9a–c), however, the corresponding carboxylic acids (10a–c) were obtained exclusively.
M. Miura, F. Akase, M. Shinohara and M. Nomura, J. Chem. Soc., Perkin Trans. 1, 1987, 1021 DOI: 10.1039/P19870001021
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