Arylsulphonylcarbenes have been generated in benzene by thermolysis of arylsulphonyldiazomethanes. Contrary to previous findings arylsulphonylcarbenes add to benzene giving the corresponding arylsulphonylcycloheptatrienes
R. Bartnik and K. Wawrynko, J. Chem. Soc., Perkin Trans. 1, 1987, 715 DOI: 10.1039/P19870000715
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