A chiral route to cis-caronaldehyde, a key intermediate of cis-pyrethroid insecticides as well as an efficient resolving agent for secondary alcohols, has been developed using D-mannitol as the starting material employing a sequential one-pot sodium periodate cleavage and Horner-Emmons condensation in an aqueous medium as the key stage.
S. Takano, A. Kurotaki, M. Takahashi and K. Ogasawara, J. Chem. Soc., Perkin Trans. 1, 1987, 91 DOI: 10.1039/P19870000091
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