Stability constants of binary complexes can be determined using linear-scan or cyclic-voltammetric data. In contrast to a recently applied graphical method, numerical treatment based on a non-linear least-squares refinement allows one to make optimal use of the information contained in the data set. This is illustrated by re-evaluating recent literature data.
H. Gampp, J. Chem. Soc., Faraday Trans. 1, 1987, 83, 1719 DOI: 10.1039/F19878301719
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