Issue 24, 1987

Reactions of 1H-1,2- and 1H-1,3-diazepines with dimethyl acetylenedicarboxylate

Abstract

The title reactions yield the 3a, 7a-dihydropyrrolo[3,2-b]pyridines (2) and 3a,7a-dihydroindazoles (9), respectively, probably via the diazonine intermediates (4) and (8) derived from the initially formed [2 + 2]π cycloadducts; the indazoles (9) further react with the reagent to give the dimethyl phthalates (6) and the pyrazoles (7)via the [4 + 2]π cycloadducts (10).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1880-1881

Reactions of 1H-1,2- and 1H-1,3-diazepines with dimethyl acetylenedicarboxylate

J. Kurita, N. Kakusawa and T. Tsuchiya, J. Chem. Soc., Chem. Commun., 1987, 1880 DOI: 10.1039/C39870001880

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements