The structure of Li5BiO5, determined by X-ray and neutron diffraction, is of the rocksalt type, but exhibits ordering of cations and anion vacancies related to that found in the ordered, low temperature TiO phase.
C. Greaves and S. M. A. Katib, J. Chem. Soc., Chem. Commun., 1987, 1828 DOI: 10.1039/C39870001828
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