Spectroelectrochemical detection of local pH changes has shown that proton expulsion accompanies redox switching of polypyrrole perchlorate thin films from the insulating to the conductive state.
E. W. Tsai, G. Jang and K. Rajeshwar, J. Chem. Soc., Chem. Commun., 1987, 1776 DOI: 10.1039/C39870001776
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