Arylamines are transformed into their ortho- and para-trifluoromethyl derivatives by the action of trifluoromethyl bromide under slight pressure in the presence of 0,15 equiv. of zinc and sulphur dioxide in dimethylformamide.
C. Wakselman and M. Tordeux, J. Chem. Soc., Chem. Commun., 1987, 1701 DOI: 10.1039/C39870001701
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