Irradiation with visible light of a mixture of an alkene in degassed aqueous acetonitrile containing tetraphenylporphyrinantimony(V) as a sensitizer, methylviologen as an electron acceptor, and hydroxide ion, induced epoxidation of the alkene accompanied by hydrogen evolution, with water acting as the electron donor.
H. Inoue, M. Sumitani, A. Sekita and M. Hida, J. Chem. Soc., Chem. Commun., 1987, 1681 DOI: 10.1039/C39870001681
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