α-Trimethylsilyl-substituted sulphoxides and sulphides undergo rearrangement with loss of the silyl group when treated respectively with trifluoroacetic anhydride and with N-halogenosuccinimide in the presence of trifluoroacetic acid, giving α-acyloxy sulphides and α-halogeno sulphides.
H. Ishibashi, H. Nakatani, K. Maruyama, K. Minami and M. Ikeda, J. Chem. Soc., Chem. Commun., 1987, 1443 DOI: 10.1039/C39870001443
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