The reaction of BH3·THF (THF = tetrahydrofuran) with (η5-C5H5)Co(PPh3)2 has resulted in the isolation and characterization of the first example of a metal-rich metallaphosphaborane.
J. Feilong, T. P. Fehlner and A. L. Rheingold, J. Chem. Soc., Chem. Commun., 1987, 1395 DOI: 10.1039/C39870001395
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