Issue 18, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

The first hexacarboxylato diruthenium(III) complex. Synthesis, X-ray crystal structure, and properties of tetra-µ-acetato-diacetatodiruthenium(III) monohydrate

Michael G. B. Drew,   Paula Higgins  and  G. Malachy McCann  

Abstract

The reaction of [Ru2(µ-OAc)4Cl] with AgOAc in AcOH/MeOH gives the red oxidation product [Ru2(µ-OAc)4(OAc)2]·H2O (1), the structure of which has been determined by X-ray crystallography; this is the first example of a paramagnetic Ru26+ complex.

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Article information

DOI
https://doi.org/10.1039/C39870001385
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1385-1387

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The first hexacarboxylato diruthenium(III) complex. Synthesis, X-ray crystal structure, and properties of tetra-µ-acetato-diacetatodiruthenium(III) monohydrate

M. G. B. Drew, P. Higgins and G. M. McCann, J. Chem. Soc., Chem. Commun., 1987, 1385 DOI: 10.1039/C39870001385

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