Analysis of the Fe K-edge extended X-ray absorption fine structure (EXAFS) with multiple scattering calculations indicates that Fe3(CO)12 adopts primarily an all-terminal carbonyl co-ordination in light petroleum solution (mean Fe–Fe distance 2.65 Å), but that there is substantial population of bridging sites in a frozen CH2Cl2 solution (mean Fe–Fe distance 2.59 Å).
N. Binsted, J. Evans, G. N. Greaves and R. J. Price, J. Chem. Soc., Chem. Commun., 1987, 1330 DOI: 10.1039/C39870001330
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