The preparation and properties of the oxide-bridged tetranuclear complex [Mn4O2(OAc)6(bpy)2](1)(bpy = 2,2′-bipyridine) are reported; the complex has an average metal oxidation state of +2.5, corresponding to the putative S–1 oxidation state of the photosynthetic water oxidation centre.
C. Christmas, J. B. Vincent, J. C. Huffman, G. Christou, H. Chang and D. N. Hendrickson, J. Chem. Soc., Chem. Commun., 1987, 1303 DOI: 10.1039/C39870001303
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