Issue 14, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

On the mechanism of peracid oxidation of α-diketones to acid anhydrides: an 17O and 18O isotope study

Paul M. Cullis,   John R. P. Arnold,   Michael Clarke,   Rachel Howell,   Miguel DeMira,   Matthew Naylor  and  Dave Nicholls  

Abstract

Peracid oxidation of 17O or 18O isotopically labelled benzil gave rise to benzoic acid anhydride in which both the bridging oxygen and the carbonyl oxygen were enriched as judged by 17O and 13C n.m.r. spectroscopy and mass spectrometry; these observations are inconsistent with a simple Baeyer–Villiger-type oxidation mechanism.

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Article information

DOI
https://doi.org/10.1039/C39870001088
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1088-1089

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On the mechanism of peracid oxidation of α-diketones to acid anhydrides: an 17O and 18O isotope study

P. M. Cullis, J. R. P. Arnold, M. Clarke, R. Howell, M. DeMira, M. Naylor and D. Nicholls, J. Chem. Soc., Chem. Commun., 1987, 1088 DOI: 10.1039/C39870001088

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