The tryptophan side chain is transformed by in situ generated ruthenium(VIII), to that of aspartic acid, in good yields; a multi-step degradation sequence is suggested on the basis of the transformations of tetrahydrocarbazole to adipic acid, valine to isobutyric acid, and phenylalanine to phenylacetic acid.
S. Ranganathan, D. Ranganathan and D. Bhattacharyya, J. Chem. Soc., Chem. Commun., 1987, 1085 DOI: 10.1039/C39870001085
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