Ab initio and MNDO calculations predict the hydroxide anion-catalysed intramolecular hydride transfer reaction of glyoxal to exhibit a larger kinetic hydrogen isotope effect than the intermolecular Cannizzaro reaction of formaldehyde.
I. H. Rajyaguru and H. S. Rzepa, J. Chem. Soc., Chem. Commun., 1987, 998 DOI: 10.1039/C39870000998
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