Reaction of titanium(III) alkyls, (η5-C5Me5)2TiR (R = Et or Prn), in toluene solution with CO2 proceeds at room temperature with formation of the titanium formate (η5-C5Me5)2TiO2CH, and the corresponding alkene (ethene or propene).
G. A. Luinstra and J. H. Teuben, J. Chem. Soc., Chem. Commun., 1987, 849 DOI: 10.1039/C39870000849
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