Issue 11, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

The first example of a d3–d3 dinuclear compound containing four-co-ordinate metal atoms sharing a pair of bridging ligands: [(ButO)2W(µ-PPh2)]2

William E. Buhro,   Malcolm H. Chisholm,   Kirsten Folting,   Bryan W. Eichhorn  and  John C. Huffman  

Abstract

(p-Tolyl)(ButO)2W[triple bond, length half m-dash]W(OBut)2(p-tolyl) and Ph2PH (2 equiv.) react in hydrocarbon solvents to give toluene (2 equiv.) and [(ButO)2W(µ-PPh2)]2 which in the solid state contains a puckered W2P2 moiety, W–W 2.59 Å; in solution the W2(µ-PPh2)2 moiety is undergoing rapid inversion on the n.m.r. time-scale.

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Article information

DOI
https://doi.org/10.1039/C39870000845
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 845-847

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The first example of a d3–d3 dinuclear compound containing four-co-ordinate metal atoms sharing a pair of bridging ligands: [(ButO)2W(µ-PPh2)]2

W. E. Buhro, M. H. Chisholm, K. Folting, B. W. Eichhorn and J. C. Huffman, J. Chem. Soc., Chem. Commun., 1987, 845 DOI: 10.1039/C39870000845

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