ortho-Functionalisation of aryl ketones with alkenes; synthesis of 3-methylindene-2-carboxylates and 3-substituted-2-acetylthiophenes from η2-(o-acetylaryl)tetracarbonylmanganese compounds with alkenes in the presence of palladium(II)
Abstract
η2-(o-Acetylaryl)tetracarbonylmanganese compounds in the presence of PdII undergo new synthetically valuable coupling reactions with methyl acrylate, methyl vinyl ketone, acrylaldehyde, allyl alcohol, and acrylonitrile.
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