Reaction of benzene-1,2-dithiol with NH4TcO4 yields, from chloroform, the dimeric complex [Tc2(bdt)4]· CHCl3(bdt = benzene-1,2-dithiolate)(1) which has a new co-ordination geometry with a Tc2S8 core consisting of two trigonal prisms joined by a quadrilateral face.
S. F. Colmanet and M. F. Mackay, J. Chem. Soc., Chem. Commun., 1987, 705 DOI: 10.1039/C39870000705
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