Issue 8, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereoselective methylation of co-ordinated phenylphosphine: crystal and molecular structure of [(R*,R*),(R*)]-[(η5-C5H5){{1,2-C6H4(PMePh)2}FePHMePh]PF6·0.5CH2Cl2

Geoffrey T. Crisp,   Geoffrey Salem,   Frederick S. Stephens  and  S. Bruce Wild  

Abstract

Reaction of (R*,R*)-[(η5-C5H5){{1,2-C6H4(PMePh)2}FePHMePh]PF6 with iodomethane in the presence of triethylamine at 20 °C produces a separable 4 : 1 mixture of [(R*,R*),(R*)]- and [(R*,R*),(S*)]-[(η5-C5H5){{1,2-C6H4(PMePh)2}FePHMePh]PF6η the crystal and molecular structure of the major [(R*,R*),(R*)] diastereoisomer is reported.

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Article information

DOI
https://doi.org/10.1039/C39870000600
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 600-602

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Stereoselective methylation of co-ordinated phenylphosphine: crystal and molecular structure of [(R*,R*),(R*)]-[(η5-C5H5){{1,2-C6H4(PMePh)2}FePHMePh]PF6·0.5CH2Cl2

G. T. Crisp, G. Salem, F. S. Stephens and S. B. Wild, J. Chem. Soc., Chem. Commun., 1987, 600 DOI: 10.1039/C39870000600

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