Penicillinacylase catalysed hydrolysis of phenylacetate esters affords the methanol derivatives (1)–(9), of moderate to high optical purity, whereas α-chymotrypsin acting on the phenylpropionate esters provides the alcohols of opposite configuration and low optical purity.
C. Fuganti, P. Grasselli, S. Servi, A. Lazzarini and P. Casati, J. Chem. Soc., Chem. Commun., 1987, 538 DOI: 10.1039/C39870000538
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