The single crystal X-ray structure of [Pd(1)](PF6)2·MeNO2[(1)= 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclo-tetradecane] shows a square planar stereochemistry with an (R,S,R,S) conformation; electrochemical reduction at –1.65 V vs. Fc/Fc+(Fc = ferrocene) in MeCN affords a highly reactive d9 palladium(I) derivative.
A. J. Blake, R. O. Gould, T. I. Hyde and M. Schröder, J. Chem. Soc., Chem. Commun., 1987, 431 DOI: 10.1039/C39870000431
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