Issue 6, 1987

An iterative procedure for the synthesis of the diprenylated coumarins balsamiferone and gravelliferone from umbelliferone via multiple [3.3] sigmatropic rearrangements

Abstract

Repeated sequences of [3.3] sigmatropic rearrangements initiated by a Claisen rearrangement permit the synthesis of the 3,6-disubstituted umbelliferone derivatives balsamiferone (4) and gravelliferone (6) from umbelliferone.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 400-402

An iterative procedure for the synthesis of the diprenylated coumarins balsamiferone and gravelliferone from umbelliferone via multiple [3.3] sigmatropic rearrangements

N. Cairns, L. M. Harwood and D. P. Astles, J. Chem. Soc., Chem. Commun., 1987, 400 DOI: 10.1039/C39870000400

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