Treatment of the α-chloro-α-silyl sulphides (1) or (5) with trisubstituted alkenes (6) in the presence of SnCl4 gave the vinyl sulphides (7) or (8), the formation of which involves a carbenium ion rearrangement controlled by the silyl group.
H. Ishibashi, H. Nakatani, H. Sakashita and M. Ikeda, J. Chem. Soc., Chem. Commun., 1987, 338 DOI: 10.1039/C39870000338
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