Issue 3, 1987

The n–π* optical activity of a ketone predicted to be optically inactive by the octant and quadrant rules: (1R,5R)-dimethyladamantan-2-one

Abstract

The title compound, which has each of its methyl groups lying in a quadrant or octant rule symmetry place, exhibits a weak positive n–π* circular dichroism Cotton effect, Δε292max.=+0.009.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 210-211

The n–π* optical activity of a ketone predicted to be optically inactive by the octant and quadrant rules: (1R,5R)-dimethyladamantan-2-one

D. A. Lightner and V. Van Toan, J. Chem. Soc., Chem. Commun., 1987, 210 DOI: 10.1039/C39870000210

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