The stereochemistry of attack on an allylsilane is more selective when the substituent on the chiral centre carrying the silyl group is larger than a methyl group, as shown by the reactions of the allylsilanes (5) and (12) with osmium tetroxide, m-chloroperbenzoic acid, and Yamamoto's methylenation reagent.
I. Fleming, A. K. Sarkar and A. P. Thomas, J. Chem. Soc., Chem. Commun., 1987, 157 DOI: 10.1039/C39870000157
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