The distribution of label of the trichothecene, 3-acetyldeoxynivalenol (3-ADN) derived from mevalonate and three of the major steps in its biosynthesis (the folding of farnesyl pyrophosphate, the methyl shifts, and the stereochemistry of oxygenation) were rigorously proven.
L. O. Zamir, Y. Nadeau, C. Nguyen, K. Devor and F. Sauriol, J. Chem. Soc., Chem. Commun., 1987, 127 DOI: 10.1039/C39870000127
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