According to MNDO semi-empirical molecular orbital calculations, the transition state structures for SN2 reactions where the corresponding SN1 processes take place very readily are dominated by anti-Hammond effects, in contrast to the normal Hammond behaviour predicted for typical SN2 reactions.
G. P. Ford and C. T. Smith, J. Chem. Soc., Chem. Commun., 1987, 44 DOI: 10.1039/C39870000044
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