Allylic ring substitution of α- and β-ionones by, respectively, anodically generated cobalt(III) acetate and bromine, is selective and efficient; in contrast direct anodic oxidation is unselective but provides a route to the novel, rearranged, carotenoid end group (7).
A. Guirado, G. P. Moss and J. H. P. Utley, J. Chem. Soc., Chem. Commun., 1987, 41 DOI: 10.1039/C39870000041
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