A mechanism, rationalising the loss of the C-4 hydrogen atom of D-glucose in the biosynthesis of the deoxystreptamine ring (2) of neomycin (3), is considered.
S. K. Goda and M. Akhtar, J. Chem. Soc., Chem. Commun., 1987, 12 DOI: 10.1039/C39870000012
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