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Issue 14, 1987
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The dependence of the solid state structures of bisparaphenylene-(3n+ 4)-crown-n ethers upon macrocyclic ring size

Abstract

X-Ray crystallography on the free BPP(3n+4)Cn ethers where n= 7,8,10,11, and 12 reveals a conformational dependence for the macrocycles which is reflected in their cavity sizes, with a maximum for n= 10, and in the relative orientations of the two hydroquinol rings, almost orthogonal for n= 7 and parallel or nearly parallel for n= 8,10,11, and 12, with respect to each other.

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Article information


J. Chem. Soc., Chem. Commun., 1987, 1070-1072
Article type
Paper

The dependence of the solid state structures of bisparaphenylene-(3n+ 4)-crown-n ethers upon macrocyclic ring size

A. M. Z. Slawin, N. Spencer, J. F. Stoddart and D. J. Williams, J. Chem. Soc., Chem. Commun., 1987, 1070
DOI: 10.1039/C39870001070

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