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Issue 13, 1987
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Observation of bridged–terminal hydrido equilibria in a series of iron–platinum bimetallic complexes

Abstract

Oxidative addition of Fe(CO)4PR2H to Pt(C2H4)(PR′3)2 gives an equilibrium mixture of (OC)3Fe(µ-PR2)(µ-H)Pt(PR′3)2 and (OC)3(H)F[graphic omitted]t(PR′3)2, the first system in which an equilibration between bridge and terminal hydride bonding modes can be observed.

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Article information


J. Chem. Soc., Chem. Commun., 1987, 1029-1031
Article type
Paper

Observation of bridged–terminal hydrido equilibria in a series of iron–platinum bimetallic complexes

J. Powell, M. R. Gregg and J. F. Sawyer, J. Chem. Soc., Chem. Commun., 1987, 1029
DOI: 10.1039/C39870001029

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