Charge-transfer interaction between N,N-dimethylaniline and aromatic sulphonyl chlorides
Abstract
The donor–acceptor interactions of N,N-dimethylaniline with toluene-p-sulphonyl chloride, toluene-o-sulphonyl chloride, and benzenesulphonyl chloride have been investigated by u.v.–visible spectroscopy. New charge-transfer bands were observed in acetonitrile medium. Equilibrium constants and thermodynamic parameters were determined.
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