Two allylic epoxides, 4β,5β-epoxycholest-6-en-3β-ol and 4α,5α-epoxycholest-6-ene-1α,3α-diol, were obtained by reaction of the corresponding conjugated dienols with t-butyl hydroperoxide in the presence of bisacetylacetonato-oxovanadium as catalyst. The reductive opening of these epoxides and other related reactions are discussed.
E. Glotter and M. Zviely, J. Chem. Soc., Perkin Trans. 1, 1986, 321 DOI: 10.1039/P19860000321
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