SCHEDULED MAINTENANCE:
Static quenching of the photoexcited state of the tris(2,2′-bipyridine(ruthenium(II) complex by colloidal prussian blue (PB) in water has been studied. The quenching behaviour has been analysed in terms of stepwise complex formation between Ru(bpy)2+3 and PB which obeys Poisson statistics. The binding of the Ru complex to the colloidal PB particle is discussed.
M. Kaneko, X. Hou and A. Yamada, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 1637 DOI: 10.1039/F19868201637
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