The syntheses and structures of [FeL3]– and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.
I. A. Latham, G. J. Leigh, C. J. Pickett, G. Huttner, I. Jibrill and J. Zubieta, J. Chem. Soc., Dalton Trans., 1986, 1181 DOI: 10.1039/DT9860001181
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