Thermodynamic and kinetic parameters have been obtained for the hydrolysis of tris(1,10phenanthroline)iron(II) in several 1,4-dioxane–water mixtures. A linear relationship was found between In k and the solvent-polarity parameter ET. This relationship is interpreted and discussed in terms of the thermodynamic excess properties of the mixtures.
M. Cazanga, J. G. Santos and F. Ibáñez, J. Chem. Soc., Dalton Trans., 1986, 465 DOI: 10.1039/DT9860000465
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